Synthesis and the magnetic properties of novel metal(II) complexes of polyamides |
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Authors: | Jiageng Liu Weilin Sun Fengcai Lu |
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Affiliation: | 1. Department of Polymer Science, Zhejiang University, Hangzhou, 310027, People's Republic of China;2. Institute of Chemistry, Chinese Academy of Science, Beijing, 100080, People's Republic of China |
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Abstract: | Novel polyamides DTPA and DTPyA are prepared from 2,2′-diamino-4,4′-bisthiazole and aromatic polycarbonyl chloride. The complexes of Fe(II) and Cu(II) metal of the polyamides are also prepared. The complexes as well as the polyamides are characterized through IR and EPR, and the magnetic property of each complex are measured through MPMS. It is found the Fe(II) complexes of both DTPA and DTPyA reveal magnetization ability, especially the Fe(II) DTPA complex. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 82: 818–822, 2001 |
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Keywords: | polyamides polymer complex synthesis characterization magnetic property |
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