| 磷钨钼酸掺杂聚苯胺催化合成缩醛（酮） |
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| 引用本文： | 杨水金,高飞,童文龙.磷钨钼酸掺杂聚苯胺催化合成缩醛（酮）[J].北京轻工业学院学报,2008(1):13-16. |
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| 作者姓名： | 杨水金 高飞 童文龙 |
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| 作者单位： | 湖北师范学院化学与环境工程系,湖北黄石435002 |
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| 基金项目： | 湖北省自然科学基金资助项目（2005ABA053）;湖北省教育厅教研基金资助项目（20060335） |
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| 摘 要： | 采用回流法制备了磷钨钼酸掺杂聚苯胺催化剂.对以环己酮、丁酮、苯甲醛和正丁醛与二元醇（乙二醇,1,2-丙二醇）为原料合成8种缩醛（酮）的反应条件进行了研究,较系统地研究了醛/酮与二元醇量比、催化剂用量、反应时间诸因素对收率的影响.结果表明,在n（醛/酮）与n（乙二醇/1,2-丙二醇）的比为1∶1.5,催化剂的用量占反应物料总质量的0.8%,反应时间为1 h条件下,8种缩醛（酮）的收率为48.3%-81.1%.
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| 关 键 词： | 磷钨钼酸 缩醛 缩酮 聚苯胺 催化 |
CATALYTIC SYNTHESIS OF ACETALS AND KETALS WITH H3PW6Mo6O40/PAn |
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| YANG Shui-jin,GAO Fei,TONG Wen-long.CATALYTIC SYNTHESIS OF ACETALS AND KETALS WITH H3PW6Mo6O40/PAn[J].Journal of Beijing Institute of Light Industry,2008(1):13-16. |
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| Authors: | YANG Shui-jin GAO Fei TONG Wen-long |
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| Affiliation: | (Department of Chemistry and Environmental Engineering, Hubei Normal University, Huangshi 435002, China ) |
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| Abstract: | A new environmental friendly catalyst, H3PW6Mo6O40/PAn was prepared by refluxing method. 8 Classes of acetals or ketals were synthesized from aldehyde/ketone and glycol in the presence of H3PW6Mo6O40/PAn. The factors influencing the synthesis were discussed and the optimum conditions were found out. The optimum conditions are： molar ratio of aldehyde/ketone to glycol is 1： 1.5, catalyst content is equal to 0.8% feed stock, and the reaction time is 1.0 h. H3PW6Mo6O40/ PAn is an excellent catalyst for synthesizing 8 classes of acetals or ketals and their yield can reach 48.3% -81.1%. |
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| Keywords: | H3PW6Mo6O40 acetals ketals polyaniline catalysis |
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