| 苯酚与碳酸二甲酯合成碳酸二苯酯催化剂的研究进展 |
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| 引用本文： | 李志会,齐旭东,王延吉.苯酚与碳酸二甲酯合成碳酸二苯酯催化剂的研究进展[J].精细石油化工,2008,25(6). |
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| 作者姓名： | 李志会 齐旭东 王延吉 |
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| 作者单位： | 1. 河北工业大学能源与环境工程学院,天津,300401
2. 河北工业大学化工学院,天津,300130 |
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| 基金项目： | 国家自然科学基金，天津市自然科学基金 |
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| 摘 要： | 介绍了苯酚与碳酸二甲酯合成碳酸二苯酯的反应原理和热力学,综述了该反应催化剂的研究进展和发展前景,认为新型高效均相催化剂的开发、传统均相催化剂的改造(加入助剂或与其他催化剂复配)、多相催化剂活性和稳定性的进一步提高将是今后碳酸二苯酯合成中研究的重点。
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| 关 键 词： | 碳酸二甲酯 碳酸二苯酯 热力学 均相催化剂 多相催化剂 |
RESEARCH PROGRESSES OF CATALYSTS FOR SYNTHESIS OF DIPHEN YL CARBONATE FROM PHENOL AND DIMETHYL CARBONATE |
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| Li Zhihui,Qi Xudong,Wang Yanji.RESEARCH PROGRESSES OF CATALYSTS FOR SYNTHESIS OF DIPHEN YL CARBONATE FROM PHENOL AND DIMETHYL CARBONATE[J].Speciality Petrochemicals,2008,25(6). |
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| Authors: | Li Zhihui Qi Xudong Wang Yanji |
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| Abstract: | The reaction principles and thermodynamics for the synthesis of diphenyl carbonate from phenol and dimethyl carbonate and the research progresses of catalysts were reviewed.It is suggested that the development of new types of homogeneous catalysts with high efficiency,the modification of traditional homogeneous catalysts with addition of promoters or combination with other catalysts,and improvement of the activity and stability of heterogeneous catalysts are the focus for the synthesis of diphenyl carbonate. |
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| Keywords: | dimethyl carbonate diphenyl carbonate thermodynamics homogeneous catalysts heterogeneous catalysts |
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