| 聚乙烯熔体接枝马来酸酐产物中残余单体的分离与表征 |
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| 引用本文： | 刘萌戈,陶礼阳,俞炜,周持兴.聚乙烯熔体接枝马来酸酐产物中残余单体的分离与表征[J].中国塑料,2005,19(9):39-41. |
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| 作者姓名： | 刘萌戈 陶礼阳 俞炜 周持兴 |
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| 作者单位： | 上海交通大学化学化工学院，上海交通大学化学化工学院，上海交通大学化学化工学院，上海交通大学化学化工学院 上海 200240，上海 200240，上海 200240，上海 200240 |
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| 基金项目： | 国家自然科学基金资助项目(编号50390090) |
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| 摘 要： | 用不同溶剂低温回流洗涤聚乙烯熔体接枝马来酸酐的产物(无凝胶的或有凝胶的),通过化学滴定监控洗出过程,拟合洗出函数,发现洗出速率受溶剂与聚合物的溶度参数差影响,与凝胶无关。对洗后样品进行化学与红外分析,证明上述分离方法可行。
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| 关 键 词： | 聚乙烯 接枝 马来酸酐 残余单体 溶度参数 |
| 文章编号： | 1001-9278（2005）09-0039-03 |
| 收稿时间： | 2005-05-03 |
| 修稿时间： | 2005-05-03 |
Separation and Characterization of Residual Monomers in Molten Polyethylene Grafted Maleic Acid Product |
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| LIU Meng-ge, TAO Li-yang, YU Wei, ZHOU Chi-xing.Separation and Characterization of Residual Monomers in Molten Polyethylene Grafted Maleic Acid Product[J].China Plastics,2005,19(9):39-41. |
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| Authors: | LIU Meng-ge TAO Li-yang YU Wei ZHOU Chi-xing |
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| Affiliation: | School of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai 200240, China |
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| Abstract: | Different solvents were used to flux and extract the product of molten polyethylene grafted maleic afcid (with or without gel) under low temperature, which was monitored by chemical tritation. It is found that the extracting rate was determined by the difference of solubility parameter between solvent and polymer, and independent to gel. Chemical and infrared analysis proved that this method was feasible. |
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| Keywords: | polyethylene graft maleic anhydride residual monomer solubility parameter |
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