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多点测量式毒气阵列检测系统研究与光谱分析
引用本文:廖海洋,吕建波,侯长军,张红英,朱彬. 多点测量式毒气阵列检测系统研究与光谱分析[J]. 光电工程, 2009, 36(1). DOI: 10.3969/j.issn.1003-501X.2009.01.013
作者姓名:廖海洋  吕建波  侯长军  张红英  朱彬
作者单位:重庆大学光电工程学院,重庆,400030;重庆大学生物工程学院,重庆,400030;重庆大学化学化工学院,重庆,400030
基金项目:国家高技术研究发展计划(863计划) 
摘    要:针对单组分毒气识别与单组分毒气痕量浓度测量的需求,本文提出了以吸收光谱为检测手段、采用多点测量技术方案的毒气阵列检测系统,并以金属卟啉为敏感物质研制了一种新型的阵列式气敏传感器.重点研究了检测系统的工作原理和两种毒气模拟品的光谱响应模式,给出了响应模式的偏最小二乘法与BP神经网络组合的识别模型和痕量浓度测量的计算算法.实验结果表明,本系统对气态甲基磷酸二甲酯(DMMP)与气态二甲苯(DMB)两种毒气模拟品和沙林、梭曼与光气三种毒气共50个未知样本预测识别的正确率为98%,两种毒气模拟品(DM肝和DMB)的最大相对测量误差为3%.

关 键 词:毒气检测  吸收光谱  多点测量  阵列式传感器  模式识别

Multi-spot Measuring Gas Array Detection System and Spectral Analysis
LIAo Hai-yang,LU Jian-bo,HOU Chang-jun,ZHANG Hong-ying,ZHU Bin. Multi-spot Measuring Gas Array Detection System and Spectral Analysis[J]. Opto-Electronic Engineering, 2009, 36(1). DOI: 10.3969/j.issn.1003-501X.2009.01.013
Authors:LIAo Hai-yang  LU Jian-bo  HOU Chang-jun  ZHANG Hong-ying  ZHU Bin
Affiliation:LIAO Hai-yanga,Lü Jian-boa,HOU Chang-junb,ZHANG Hong-yingc,ZHU Bina ( a. College of Opto-electronic Engineering,b. Bioengineering College of Chongqing University,c. College of Chemistry and Chemical Engineering,Chongqing University,Chongqing 400030,China )
Abstract:In allusion to the requirement of single-component gases identification and trace concentration measure, a gas array inspect system is put forward based on absorption spectrum measure and multi-spot measure technology, and a novel array gas-sensitive sensor is developed which takes metallic porphyrin as sensitive material. In addition, the principle of the system and the spectral response pattern for two kinds of gaseous simulacrums are mainly researched, and partial least square combined with BP neural net...
Keywords:gas-detecting  absorption spectrum  multi-spot measuring  array-sensor  pattern recognition  
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