| 丙烷均相氧化脱氢及其应用 |
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| 引用本文： | 王宗祥 匡洞庭. 丙烷均相氧化脱氢及其应用[J]. 石油学报(石油加工), 1996, 12(1): 1-6 |
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| 作者姓名： | 王宗祥 匡洞庭 |
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| 作者单位： | 大庆石油学院石油化工系 |
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| 摘 要： | 丙烷在８００￣８４０Ｋ、Ｏ２／Ｃ３＾０比０．４４￣１．６５、停留时间６．０￣１３．５ｓ的条件下进行均相氧化脱氢。在丙烷转化率为４０％时，丙烯选择性为４２．５％，产率为１７．０％。用自丙烯生产丙烯醛的Ｍｏ－Ｃｏ－Ｒｅ－Ｂｉ－Ｏ催化剂，将上述反应产物在５９０￣６１５Ｋ、Ｏ２／Ｃ３＾０综合比０．６５￣１．１３、停留时间２．４￣４．２ｓ的条件下氧化，得到丙烯醛按丙烷衡算的选择性〉３３．５％，产率〉１３．５
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| 关 键 词： | 丙烷 均相氧化脱氢 丙烯 丙烯醛 |
HOMOGENEOUS OXIDATIVE DEHYDROGENATION OF PROPANE AND ITS APPLICATION FOR PRODUCING CHEMICALS |
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| Wang Zongxiang Kuang Dongting Mao Guoliang Zhao Rusong Liu Guangshun. HOMOGENEOUS OXIDATIVE DEHYDROGENATION OF PROPANE AND ITS APPLICATION FOR PRODUCING CHEMICALS[J]. Acta Petrolei Sinica (Petroleum Processing Section), 1996, 12(1): 1-6 |
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| Authors: | Wang Zongxiang Kuang Dongting Mao Guoliang Zhao Rusong Liu Guangshun |
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| Abstract: | Homogeneous oxidative dehydrogenation of propane was studied at temperatures of 800 840K,oxygen/prppane ratio of 0 44 1 65 and residence time of 6 0 13 5s.At 40 0% conversion of propane,the selectivity and yield of propylene obtained were 42 5% and 17 0%,respectively.Then the reaction product was passed over Mo Co Re Bi O catalyst at temperatures of 590 615K,total oxygen/propane ratios of 0 65 1 13 and residence time of 2 4 4 2s for oxidizing the product propylene into acrolein,on the basis of prppane the selectivity and yield of acrolein were >33 5% and >13 5% respectively.The results obtained are comparable to those from direct catalytic oxidation of propane into acrolein as reported in literature. |
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| Keywords: | propane homogeneous oxidative dehydrogenation propene acrolein |
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