| 采用探针分子对长链烷烃异构化反应机理研究进展 |
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| 引用本文： | 国海峰,杨晓东,郭峰.采用探针分子对长链烷烃异构化反应机理研究进展[J].化工生产与技术,2011,18(1):55-58,10. |
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| 作者姓名： | 国海峰 杨晓东 郭峰 |
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| 作者单位： | 大庆化工研究中心,黑龙江,大庆,163714 |
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| 摘 要： | 介绍了目前世界上存在的长链烷烃异构化反应的催化机理,列举了近年来研究者根据各自不同的研究背景,采用探针分子方法对该机理进行的研究,结果所支持的观点主要有择形催化、孔口催化和Key-Lock催化.根据存在的争议和研究现状对探针分子提出了新的构想,认为针对催化剂特殊的十元环孔道结构,寻求设计出具有特定结构的探针分子,通过这...
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| 关 键 词： | 探针分子 长链烷烃 异构化 反应机理 |
Progress of the Probe Molecules to Analyze the Mechanism of High Alkanes in Isomerization Reaction |
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| Guo Haifeng,Yang Xiaodong,Guo Feng.Progress of the Probe Molecules to Analyze the Mechanism of High Alkanes in Isomerization Reaction[J].Chemical Production and Technology,2011,18(1):55-58,10. |
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| Authors: | Guo Haifeng Yang Xiaodong Guo Feng |
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| Affiliation: | (Daqing Chemical Research Center,Daqing,Heilongjiang 163714) |
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| Abstract: | The mechanism of high alkanes in isomerization reaction were introduced.Under the different backgrounds,researchers took the method of probe molecules to study the mechanism.The main ideas they pointed were shape-selective catalysis,pore mouth catalysis and Key-Lock catalysis.According to the debates and the current situation,a new idea about the probe molecules was given in this article. |
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| Keywords: | probe molecule high-alkane isomerization |
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