| 石蜡、微晶蜡非催化氧化的研究 |
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| 引用本文： | 沈本贤,冯玉海,高晋生.石蜡、微晶蜡非催化氧化的研究[J].石油炼制与化工,2001,32(11):52-55. |
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| 作者姓名： | 沈本贤 冯玉海 高晋生 |
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| 作者单位： | 华东理工大学石油加工研究所,上海,200237 |
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| 基金项目： | 中石化集团公司资助项目(199038). |
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| 摘 要： | 在实验室对石蜡、微晶蜡非催化空气氧化进行了研究，考察了反应时间、反应温度和空气流量对其反应过程的影响及其差异。结果表明，异构烷烃含量高的微晶蜡比石蜡容易发生氧化的反应；石蜡及微晶蜡的氧化产物组成相似，是由脂肪酸、酯、铜等含氧化合物组成。
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| 关 键 词： | 石蜡 微晶蜡 空气氧化 皂化值 酸值 非催化氧化 |
| 修稿时间： | 2000年11月20 |
STUDY ON NON-CATALYTIC OXIDATION OF PARAFFIN WAX AND MICROCRYSTILLINE WAX |
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| Shen Benxian,Feng Yuhai,Gao Jinsheng.STUDY ON NON-CATALYTIC OXIDATION OF PARAFFIN WAX AND MICROCRYSTILLINE WAX[J].Petroleum Processing and Petrochemicals,2001,32(11):52-55. |
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| Authors: | Shen Benxian Feng Yuhai Gao Jinsheng |
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| Abstract: | Non catalytic oxidation of paraffin wax and microcrystalline wax was studied in the laboratory. The effects of oxidation temperature, air velocity and reaction time on the oxidation course were investigated. The test results showed that more iso-paraffin contained microcrystalline wax could be oxidized easier than paraffin wax. The compositions of the oxidization products of paraffin wax and microcrystalline wax were similar, which mainly composed of fatty acids, esters and ketones. |
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| Keywords: | paraffin wax microcrystalline wax air oxidation saponification number acid number |
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