新型淀粉基吸附材料对Cr~(3+)吸附性能的研究 |
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引用本文: | 韩敏,宋瑞娟,李仲谨.新型淀粉基吸附材料对Cr~(3+)吸附性能的研究[J].应用化工,2009,38(8):1105-1108. |
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作者姓名: | 韩敏 宋瑞娟 李仲谨 |
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作者单位: | 1. 西安文理学院,化学系,陕西,西安,710065 2. 陕西科技大学,化学与化工学院,陕西,西安,710021 |
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基金项目: | 国家自然科学基金资助项目 |
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摘 要: | 以可溶性淀粉为原料,N,N’-亚甲基双丙烯酰胺为预交联剂,环氧氯丙烷为交联剂,采用反相悬浮聚合得到了一种新型淀粉基吸附材料-淀粉微球,研究了微球对Cr3+的吸附行为。结果表明,微球对Cr3+吸附行为符合Langmiur方程和Freundlich方程;吸附Cr3+使微球的结晶结构被进一步破坏,结晶度下降。
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关 键 词: | 淀粉基 离子吸附 Cr3+ |
Study on adsorption behavior of novel starch-based adsorption material for chromium ions |
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Abstract: | The starch microspheres were synthesized from soluble starch as raw material through inverse-suspension polymerization,using N,N'-methylenebisacrylamide as precrosslinking agent,epichlorohydrin as the crosslinking agent.Adsorption behavior of starch graft copolymer microspheres for Cr3+ was investigated.The result shows that the adsorption behavior of the copolymer microspheres for Cr3+ is adapted to Langmiur and Freundlich adsorption isotherm equation.After Cr3+ was adsorbed in microspheres,the crystallinity of graft copolymer microspheres decreased. |
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Keywords: | Cr3+ |
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