Liquid-phase synthesis of SrCo0.9Nb0.1O3-δ cathode material for proton-conducting solid oxide fuel cells

A novel liquid-phase synthesis strategy is demonstrated for the preparation of the Nb-containing ceramic oxide SrCo_0.9Nb_0.1O_3-δ (SCN). In comparison with the traditional solid-state reaction (SSR) method, the liquid-phase synthesis route offers a couple of advantages, including a lower phase formation temperature and a smaller particle size of the SCN materials that are beneficial for applications as proton-conducting fuel cell cathode. With BaCe_0.4Zr_0.4Y_0.2O_3-δ (BCZY442) as the electrolyte and the SCN synthesized in this work as the cathode, a proton-conducting solid oxide fuel cell (SOFC) shows a peak power density of 348 mW cm^?2 at 700 °C, significantly higher than that of a SOFC fabricated with SCN cathode prepared using the SSR method, which can only deliver 204 mW cm^?2 at the same temperature. Additionally, this new synthesis strategy allows impregnation of Sr²⁺, Co³⁺and Nb⁵⁺ on the solid backbone in aqueous solution, further improving cell performance to reach a peak power density of 488 mW cm^?2 at 700 °C.