Spin-orbit coupling in manganese doped calcium molybdato-tungstates |
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| Authors: | T Groń M Pawlikowska E Tomaszewicz M Oboz B Sawicki H Duda |
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| Affiliation: | 1. Institute of Physics, University of Silesia, ul. Uniwersytecka 4, 40-007 Katowice, Poland;2. Department of Inorganic and Analytical Chemistry, Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology, Al. Piastów 42, 71-065 Szczecin, Poland |
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| Abstract: | The manganese doped calcium molybdato-tungstates with the formula of Ca1-xMnx(MoO4)0.50(WO4)0.50 (x = 0.01, 0.03, 0.05, 0.10, 0.125, and 0.15) were successfully obtained by two-step synthesis using in both steps a solid state reaction route. All ceramics show scheelite-type tetragonal structure with space group I41/a. The electrical and magnetic studies within the temperature range of 2–300 K showed a weak p-type electrical conductivity and the paramagnetic state of Mn-doped ceramic materials. With increasing Mn content in samples under study, a change in the short-range interactions from ferromagnetic to antiferromagnetic as well as an increase in the orbital contribution to the magnetic moment, resulting in a strong spin-orbit coupling, were observed. The Brillouin procedure was used to estimate the Landé factor. |
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| Keywords: | A Sintering D Scheelites C Electrical properties C Magnetic properties |
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