| 高固色率活性蓝染料KN-FB的开发研究 |
| |
| 引用本文： | 尹志刚,赵德丰. 高固色率活性蓝染料KN-FB的开发研究[J]. 现代化工, 2001, 21(9): 22-25 |
| |
| 作者姓名： | 尹志刚 赵德丰 |
| |
| 作者单位： | 尹志刚（大连理工大学染料及表面活性剂国家重点实验室大连116012） 赵德丰（大连理工大学染料及表面活性剂国家重点实验室大连116012） |
| |
| 基金项目： | 国家"九五”攻关项目(96-549-02-06). |
| |
| 摘 要： | 由2-氯-5-硝基苯磺酸钠为起始原料,经过氯磺化、亚磺化、羟乙基化、胺解、酰化、硝基还原、缩合和闭环酯化等8步反应合成出高固色率活性蓝染料KN-FB,总收率达50%以上,其各项性能指标均达到或超过国外商品染料RemazolBrilliantBlueFB的水平.对合成中间体进行了结构表征,并找出各步反应的稳定条件.
|
| 关 键 词： | 三苯二噁嗪 活性染料KN-FB 合成工艺 结构鉴定 染料 |
| 修稿时间： | 2001-03-29 |
Study on developing of reactive blue dye KN-FB with high fixing efficiency |
| |
| YIN Zhi gang,ZHAO De feng. Study on developing of reactive blue dye KN-FB with high fixing efficiency[J]. Modern Chemical Industry, 2001, 21(9): 22-25 |
| |
| Authors: | YIN Zhi gang ZHAO De feng |
| |
| Abstract: | A reactive blue dye KN FB with excellent fixing efficiency was synthesized using sodium 2 chloro 5 nitrobenzenesulfonate as starting material via chlorosulfonation,sulfination,hydroxyethylation,amination,acylation,reduction,condensation,ring closure and esterification and so on.The total yield of final dye was reached over 50 %,and its performance and quality index were all reached or surpassed the level of the same kind of foreign commercial product,Remazol Brilliant Blue FB.The structure of those obtained intermediates were characterized or identified by IR,NMR,MS and element analysis,and the conditions of above mentioned reactions were optimized. |
| |
| Keywords: | triphenyl dioxazine reactive blue dye KN FB synthetic technology structure identification dye |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
