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Optical and electrical characterization of hafnium oxide deposited by liquid injection atomic layer deposition
Authors:P Taechakumput  S Taylor  O Buiu  RJ Potter  PR Chalker  AC Jones
Affiliation:aDepartment of Electrical Engineering and Electronics, University of Liverpool, Liverpool L69 3GJ, UK;bDepartment of Material Science and Engineering, University of Liverpool, Liverpool L69 3BX, UK;cDepartment of Chemistry, University of Liverpool, Liverpool L69 3ZD, UK
Abstract:Optical and electrical properties of a set of high-k dielectric HfO2 films, deposited by liquid injection atomic layer deposition (LI-ALD) and post deposition annealed (PDA) in nitrogen (N2) ambient at various temperatures (400–600 °C), were investigated. The films were prepared using the cyclopentadienyl of hafnium precursor Cp2Hf(CH3)2] with water deposited at 340 °C. The spectroscopic ellipsometric (SE) results show that the characteristics of the dielectric functions of these films are strongly affected by annealing temperatures. IV results show that N2-based PDA enhances the average energy depth of the shallow trapping defects from Poole–Frenkel conduction fitting. This also correlated with the measured increase in MOS capacitance–voltage hysteresis.
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