| 单核镍(Ⅱ)配合物的合成、表征和性质 |
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| 引用本文： | 陈彦国,廖展如.单核镍(Ⅱ)配合物的合成、表征和性质[J].应用化工,2000,29(4):19-20. |
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| 作者姓名： | 陈彦国 廖展如 |
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| 作者单位： | 1. 湖北师范学院化学系,湖北,黄石,435002
2. 华中师范大学化学系,湖北,武汉,430079 |
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| 摘 要： | 报道了配体N ,N—二 (2—苯并咪唑甲基 )亚胺 (简写为IDB)及含镍 (Ⅱ )单核配合物 Ni(IDB) 2 ]·Cl2 ·2CH3CH2 OH·2H2 O(Ⅰ )的合成 ,对 (Ⅰ )进行了元素分析、摩尔电导、紫外—可见光谱、红外光谱、自旋共振谱和循环伏安研究。推测配合物 (Ⅰ )的中心离子镍 (Ⅱ )为六配位八面体结构。
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| 关 键 词： | 镍(Ⅱ)单核配合物 合成 表征 |
Synthesis and characterization of the mononuclear nick el(Ⅱ) complex and its properties |
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| CHEN Yan-guo,LIAO Zhan-ru.Synthesis and characterization of the mononuclear nick el(Ⅱ) complex and its properties[J].Applied chemical industry,2000,29(4):19-20. |
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| Authors: | CHEN Yan-guo LIAO Zhan-ru |
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| Abstract: | The synthesis of a tridentate(N 3)ligand N,N di(2′ benzimidazolylmethyl)imino](IDB) and a mononuclear nickel(Ⅱ) complex Ni(IDB) 2]·Cl 2 ·2CH 3CH 2OH·2H 2O(Ⅰ) is reported. The elemental analyses、molar conductivity、ultraviolet and visible(UV Vis)、infrared(IR)、electron spin resonance(ESR) and cyclic voltammetry (CV) of the complex has been studied. Its coordination geometry may be close to octahedron or distorted octahedron. |
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| Keywords: | mononuclear nickel(Ⅱ) complex synthesis characterizatioh |
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