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Crystalline polythiophene film prepared by electrochemical polymerization of thiophene at a nickel electrode |
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| Authors: | Chun Li Gaoquan Shi Yingqiu Liang Zhaolin Sha |
| Affiliation: | a Department of Chemistry and National Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, People's Republic of China |
| Abstract: | Crystalline polythiophene (Pth) film was first electrochemically deposited onto a nickel substrate from freshly distilled BF3-diethyl ether (BFEE) solution containing 15 mM thiophene. The crystalline film was studied by the X-ray diffraction technique and it was found to be a monoclinic unit cell with parameters a = 0.624 nm, b = 0.593 nm, c = 0.596 nm, and β = 103.6°. The film obtained from this medium has a compact morphology and great strength. © 1997 Elsevier Science Ltd. |
| Keywords: | Plastic films Aromatic polymers Sulfur compounds Crystalline materials Film preparation Electropolymerization Nickel Electrochemical electrodes X ray crystallography Morphology Strength of materials Ethers Polythiophene Diethyl ether |
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