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磁性TiO_2/Fe_3O_4/黏土-SA_(01)复合光催化剂的制备及其光催化性能
引用本文:萨嘎拉,桑志茹,张宇,斯琴塔娜,照日格图.磁性TiO_2/Fe_3O_4/黏土-SA_(01)复合光催化剂的制备及其光催化性能[J].非金属矿,2010,33(2).
作者姓名:萨嘎拉  桑志茹  张宇  斯琴塔娜  照日格图
作者单位:内蒙古师范大学化学与环境科学学院天然气化工与材料科学实验室内蒙古自治区功能材料物理与化学重点实验室,呼和浩特,010022
摘    要:以黏土-SA01为载体,用共沉淀法制得Fe3O4/黏土-SA01,再以钛酸四丁酯为原料采用溶胶—凝胶法制备了TiO2/Fe3O4/黏土-SA01复合光催化剂。运用FT-IR、XRD、DRS、BET、VSM测试方法对所制得TiO2/Fe3O4/黏土-SA01复合光催化剂进行表征,该复合光催化剂包含有Fe3O4和TiO2成分。并通过在紫外光照射下对偶氮砷染料的脱色反应,表明了照射时间为60min、催化剂投加量为0.1g、偶氮染料溶液的pH值为2和初始浓度为10mg/L等最佳条件下,该复合光催化剂对偶氮染料的脱色率可达98%。

关 键 词:黏土-SA_(0.1_  偶氯砷染料  磁性  复合催化荆

Study on Preparation and Photocatalytic Performance of TiO_2/Fe_3O_4/Modified Hangjin 2~# Clay magnetic Composite Catalyst
Sa Gara,Sang Zhiru,Zhang Yu,Si Qintana,Zhao Rigetu.Study on Preparation and Photocatalytic Performance of TiO_2/Fe_3O_4/Modified Hangjin 2~# Clay magnetic Composite Catalyst[J].Non-metallic Mines,2010,33(2).
Authors:Sa Gara  Sang Zhiru  Zhang Yu  Si Qintana  Zhao Rigetu
Abstract:Using the modified Hangiin 2~# clay as carrier, the Fe_3O_4/modified Hangjin 2~# clay was prepared by coprecipitation method, then TiO_2/ Fe_3O_4/modified Hangjin 2~# clay magnetic composite catalyst was prepared using the sol-gel method with tetrabutyltitanate and Fe_3O_4/modified Hangjin 2~# clay as raw materials. The catalysts were characterized by FT-IR, XRD, DRS, BET and VSM. Photocatalytic decolorization of azo arsenic dye was examined in aqueous suspension under UV irradiation. The result showed that the decolorization ratio could reach 98% with the best conditions:irradiation time was 60 min, catalyst dosage was 0.1g, pH value of solution was 2 and initial concentration of dye solution was 10mg/L.
Keywords:clay-SA_(01)  azo arsenic dye  magnetism  composite catalyst
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