A novel process to form a silica-like thin layer on polyethylene terephthalate film and its application for gas barrier |
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Authors: | Peixin Zhu Junhui Xiang Won-Seon Seo |
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Affiliation: | a Nagoya University, Graduate School of Engineering, Nagoya 464-8603, Japan b Korea Institute of Ceramic Engineering and Technology, 233-5, Seoul, Korea |
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Abstract: | A novel process for polyethylene terephthalate (PET) surface modification with a silica-like thin layer is proposed. 3-Aminopropyltrimethoxysilane was employed to react with acetone to form dimethyliminopropyltrimethoxysilane (DIPTMS) after aging for 10 days at room temperature. After hydrolysis of alkoxy groups in DIPTMS, dimethylimine-modified silica clusters occurred resulting in an increase of the solution viscosity. Consequently, a dense and homogeneous thin layer was easily dip-coated onto a PET film. After heat treatment at 150 °C, a smooth, flexible and transparent silica-like film (about 70 nm thick) was formed via dehydration and condensation. The surface of the PET dramatically changed from hydrophobic (water contact angle: 70±2°) to hydrophilic (45±3°). As an attempt for application, a dense film of lithium metasilicate (Li2O·2SiO2·nH2O) was successfully prepared by dip coating on the modified PET film, which appeared very low oxygen permeability of about 0.17 cm3/m2 day atm at 23 °C and 85% humidity. |
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Keywords: | PET Gas barrier coatings Silicon oxide Lithium metasilicate Coatings Polymers Surface and interface states |
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