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热处理共聚醚酯的X光衍射研究
引用本文:魏俊富,边栋材. 热处理共聚醚酯的X光衍射研究[J]. 天津工业大学学报, 1996, 0(4)
作者姓名:魏俊富  边栋材
作者单位:天津纺织工学院材料科学系
摘    要:采用SAXS和WAXS技术,对不同温度热处理的PBT-PEG无规多嵌段共聚醚酯的相变化进行研究.结果表明,随着热处理温度的提高,结晶区体积增大,且主要是侧向增长,同时无定形区的体积也增加,两相间过渡层变薄,趋于形成理想的两相结构.

关 键 词:X-射线衍射,共聚醚酯,两相结构,热处理

The morphological study of annealed copoly (ether-ester) by X-ray diffractometry
Wei Junfu Bian Dongcai. The morphological study of annealed copoly (ether-ester) by X-ray diffractometry[J]. Journal of Tianjin Polytechnic University, 1996, 0(4)
Authors:Wei Junfu Bian Dongcai
Affiliation:Dept. of Materials Sci.
Abstract:The annealing induced morphological changes in random block copoly (ether-ester)s are investigated by SAXS and WAXD. The copolymer is based on polybutylene terephthalate and poly ethylene glycol. Results indicate that the volume of crystallits increases, which is mainly due to the lateral growth of the lamellae, with increasing the annealing temperatures. Meanwhile, the volume of amorphous domains increases, diffuse boundary zone existing between two phases becomes thin and the structure tends to be ideal two phase model.
Keywords:X-ray diffractometry   block copoly(ether-ester)   two-phase structure   annealing  
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