Hydrothermal synthesis of BaTiO3 from different Ti-precursors and microstructural and electrical properties of sintered samples with submicrometric grain size |
| |
Authors: | HA Ávila LA Ramajo MM Reboredo MS Castro R Parra |
| |
Affiliation: | Instituto de Investigaciones en Ciencia y Tecnología de Materiales (INTEMA), UNMdP – CONICET, J. B. Justo 4302, B7608FDQ Mar del Plata, Argentina |
| |
Abstract: | Barium titanate submicrometric particles were synthesized at 180 °C in a closed PTFE-lined stainless steel reactor with continuous stirring. Precursors used for titanium were Degussa P25 TiO2 or titanium isopropoxide (TIP). Barium hydroxide (Ba(OH)2) was added in a Ba/Ti = 1.1 molar ratio and KOH was used as mineralizer. The obtained powders were characterized by XRD and Raman spectroscopy. Powders were uniaxially pressed into discs and sintered at 1250 °C. The resulting microstructures were characterized by XRD, SEM, and Raman spectroscopy. Electrical measurements were carried out in order to characterize the ferroelectric behavior. The Ti precursor determined the sample density and grain size distribution and, consequently, the electrical response. |
| |
Keywords: | C Electrical properties BaTiO3 Hydrothermal Microstructure |
本文献已被 ScienceDirect 等数据库收录! |