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Growth and characterization of 4-methyl benzene sulfonamide single crystals
Affiliation:1. Department of Physics, Presidency College, Chennai, India;2. Department of Physics, P.B. College of Engineering, Chennai, India;3. Department of Physics, Rajalakshmi Institute of Technology, Chennai, India;1. Laboratory of Crystal Physics, Kirensky Institute of Physics, SB RAS, Akademgorodok, Krasnoyarsk 660036, Russia;2. Laboratory of Coherent Optics, Kirensky Institute of Physics, SB RAS, Akademgorodok, Krasnoyarsk 660036, Russia;3. Laboratory of Nanodiagnostics and Nanolithography, Institute of Semiconductor Physics, SB RAS, Novosibirsk 630090, Russia;4. Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk 630090, Russia;5. Functional Electronics Laboratory, Tomsk State University, Tomsk 634050, Russia;6. Novosibirsk State University, Novosibirsk 630090, Russia;1. Faculty of Chemistry, University of Wroclaw, 14 F. Joliot-Curie Str., 50-383 Wroclaw, Poland;2. Department of Chemistry, Kyiv National Taras Shevchenko University, Volodymyrska str. 64, Kyiv 01601, Ukraine;1. Nanostructured Materials Lab., Advanced Material Department, Central Metallurgical R&D Institute (CMRDI), P.O. Box 78 Helwan, 11421 Cairo, Egypt;2. Electrochemical and Chemical Treatment Lab., Minerals Department, Central Metallurgical R&D Institute (CMRDI), P.O. Box 78 Helwan, 11421 Cairo, Egypt;1. Université de Lyon, CNRS, France;2. MATEIS, Insa-Lyon, CNRS UMR5510, F-69621 Villeurbanne, France;3. Laboratoire des Matériaux Non Métalliques, IOMP, Université Ferhat Abbas, Sétif 19000, Algeria;1. Hacettepe University, Department of Physics Engineering, 06800 Beytepe, Ankara, Turkey;2. Kafkas University, Faculty of Arts and Sciences, Department of Physics, 36100 Kars, Turkey;1. Graduated School of Engineering, Toyo University, 2100 Kujirai, Kawagoe, Saitama 350-8585, Japan;2. Faculty of Science and Engineering, Toyo University, 2100 Kujirai, Kawagoe, Saitama 350-8585, Japan
Abstract:Single crystals of 4-methyl benzene sulfonamide (4MBS) were successfully grown from aqueous solution by low temperature solution growth technique. The grown crystal was characterized by single crystal XRD and powder XRD methods to obtain the lattice parameters and the diffraction planes of the crystal. UV–vis–NIR absorption spectrum was used to measure the range of optical transmittance and optical band gap energy. The optical transmission range was measured as 250–1200 nm. FTIR spectral studies were carried out to identify the presence of functional groups in the grown crystal. The thermal behavior of the crystal was investigated from thermo gravimetric analysis (TGA) and differential scanning calorimetry (DSC) study. The absence of SHG was noticed by Kurtz and Perry powder technique. The third order NLO behavior of the material was confirmed by measuring the nonlinear optical properties using Z-scan technique and it was found that the crystal is capable of exhibiting saturation absorption and self-defocusing performance.
Keywords:Solution growth method  Single crystal and powder XRD  UV–vis–NIR absorption  FTIR spectrum  Third order non-linear property
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