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Influence of W5+ ions on the optical properties of doped Bi12TiO20
Affiliation:1. Instituto de Fisica, Universidade Federal de Uberlandia, CEP38408-902 Uberlandia, Minas Gerais, Brazil;2. CIMAP – Centre de recherche sur les Ions, les Matériaux et la Photonique UMR 6252 CEA-CNRS-ENSICAEN-Université de Caen, 14050 CAEN Cedex 4, France;3. Instituto de Física de São Carlos, Universidade de São Paulo, USP, CEP 13560-970 São Carlos, SP, Brazil;1. Key Laboratory of Interface Science and Engineering in Advanced Materials, Taiyuan University of Technology, Ministry of Education, Taiyuan 030024, Shanxi, PR China;2. Research Center of Advanced Materials Science and Technology, Taiyuan University of Technology, Taiyuan 030024, Shanxi, PR China;3. College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, PR China;4. College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, PR China;1. Institute of Physics, Wroclaw University of Technology, Wybrzeze Wyspianskiego 27, 50-370 Wroclaw, Poland;2. Belarusian State University of Informatics and Radioelectronics, P. Browki Str. 6, 220013 Minsk, Belarus;1. Nankai University School of Medicine, Nankai University, 94 Weijin Road, Tianjin 300071, PR China;2. State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, PR China
Abstract:There have been studied single crystals of undoped and doped Bi12TiO20 with two concentrations of W5+ (2.62 × 1017 cm?3 and 2.62 × 1018 cm?3). There have been obtained absorption spectra in the energy range of 10,482–15,408 cm?1 by classical measurements. There have been determined the cross-section (σa) of the impurity absorption and the oscillator strength of dd transitions. There have been calculated the refractive index of doped crystals and the concentration of Ti3+ ions in an undoped sample through an experiment.
Keywords:Doped crystals  Impurity absorption  Oscillator strength  Refractive index
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