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Polymerization of trithiane |
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| Authors: | Jun-Ichi Takeda Koichiro Hayashi Seizo Okamura |
| Abstract: | The catalytic solid-state polymerization of trithane to polythiomethylene has been studied. The polymerization can be initiated by wide varieties of substances such as metal salts, halogen, and active organic halides. The polymerization proceeds in solid-state without topochemical process. The catalytic irreversible degradation of polythiomethylene to dimethyl sulfide and carbon disulfide has been observed. |
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