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Effects of Ce, La and Ba addition on the electrochemical behavior of super duplex stainless steels
Authors:Yun-Ha Yoo  Jung-Gu Kim  Yong-Soo Park
Affiliation:a Department of Advanced Materials Engineering, Sungkyunkwan University, 300 Chunchun-Dong, Jangan-Gu, Suwon 440-746, South Korea
b Department of Metallurgical Engineering, Yonsei University, 134 Shinchon-Dong, Seodaemun-Gu, Seoul 120-749, South Korea
Abstract:The effects of rare earth metal (REM: Ce, La) and Ba addition on aqueous corrosion properties of super duplex stainless steels (SDSS) were investigated by electrochemical tests and surface analyses. The results of potentiodynamic test indicated that the passive range increased by the addition of Ce, La, and Ba, indicating increased relative resistance to localized corrosion. The EIS measurements showed that the Ce-La-Ba-bearing alloys exhibited higher Rct and Rp values than the Ce-La-Ba-free alloy at the passive and breakdown states. Furthermore, the additions of REMs and Ba together promoted the formation of dense chromium-enriched passive film.
Keywords:A  Stainless steel  B  EIS  C  Passivity
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