Species Transport from Post-Flashover Fires

A study was performed to determine the use of an equivalence ratio to predict gas levels (CO, CO₂, O₂, and unburned hydrocarbons) transported to locations remote from a post-flashover compartment fire. A series of tests were conducted in a reduced-scale facility to measure the evolution of post-flashover compartment fire gases flowing down a hallway. Test variables included air entrainment into gases in the hallway, stoichiometry of the compartment fire gases entering the hallway, mass flow rate of compartment fire gases, and the presence of a vitiated smoke layer accumulated in the hallway. In cases with no layer accumulated in the hallway, species yields in the hallway were found to correlate with a control volume equivalence ratio. The control volume equivalence ratio is the ratio of the mass loss rate of fuel inside the compartment to the air flow into the compartment plus the air entrained into compartment fire gases flowing along the hallway. Layers that accumulate in the hallway were determined to limit oxidation, which in some cases resulted in CO yields transported to remote locations being 20% higher than those inside the compartment. Based on the experimental data, a methodology was developed for predicting species levels transported to remote locations.