Catalytic synthesis of N-alkylacrylamide from acrylonitrile and alcohol with solid acids |
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Authors: | Toshio Okuhara Xin Chen Hideho Matsuda |
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Affiliation: | Graduate School of Environmental Earth Science, Hokkaido University, Sapporo 060-0810, Japan |
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Abstract: | Catalytic synthesis of N-alkylacrylamides, which are useful monomers for functional polymers, from acrylonitrile and alcohols, such as 1-adamantanol, tert-butyl alcohol, and isopropyl alcohol has been studied using various solid acids including heteropoly compounds and zeolites. For the reaction with 1-adamantanol or tert-butyl alcohol, a heteropoly compound, Cs2.5H0.5PW12O40, exhibited a high catalytic performance and water-tolerance. On the other hand, for the synthesis of N-isopropylacrylamide from isopropyl alcohol, a high-silica zeolite, H-ZSM-5 with Si/Al ratio of 37, showed an exceptionally high activity, while it was less active in the reaction with tert-butyl alcohol or 1-adamantanol. This marked effect of reactant alcohol observed for H-ZSM-5 is probably due to shape selectivity. The prominent performance for N-isopropylacrylamide synthesis is attributable to a steric effect of the constrained pores; two reactants might be arranged adequately to form an intermediate in the pores. |
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Keywords: | Zeolites Heteropoly compounds Ritter-type reaction N-isopropylacrylamide Acrylonitrile Isopropyl alcohol |
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