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LiNi0.77Al0.03Co0.2O2正极材料研究
引用本文:顾健,顾大明,史鹏飞.LiNi0.77Al0.03Co0.2O2正极材料研究[J].电池,2004,34(3):171-172.
作者姓名:顾健  顾大明  史鹏飞
作者单位:哈尔滨工业大学理学院,黑龙江,哈尔滨,150001;哈尔滨工业大学理学院,黑龙江,哈尔滨,150001;哈尔滨工业大学理学院,黑龙江,哈尔滨,150001
摘    要:采用液相共沉淀法,得到LiNi0.77Al0.03Co0.2O2正极材料,对材料进行结构和电化学性能测试.研究发现:该材料的电化学性能比LiNiO2有很大的提高,其首次充放电比容量分别为175 mAh/g和168 mAh/g,首次充放电效率为96.4%,30次循环后放电容量保持在167 mAh/g,循环效率达到98.5%以上.

关 键 词:共沉淀  正极材料  比容量  循环性能
文章编号:1001-1579(2004)03-0171-02
修稿时间:2003年8月5日

The study of LiNi0.77Al0.03Co0.2O2 cathode material
GU Jian,GU Da-ming,SHI Peng-fei.The study of LiNi0.77Al0.03Co0.2O2 cathode material[J].Battery Bimonthly,2004,34(3):171-172.
Authors:GU Jian  GU Da-ming  SHI Peng-fei
Abstract:Cathode material LiNi_(0.77)Al_(0.03)Co_(0.2)O_2 was synthesized by a coprecipitation method and its structure and electrochemical properties was tested. The results showed that the properties of the material were considerably enhanced. Its initial charge-discharge specific capacity were 175 mAh/g and 168 mAh/g respectively with the cycle efficiency of 96.4%. Its discharge specific capacity could still retain 167 mAh/g after 30 cycles and coulombic efficiency was over 98.5%.
Keywords:coprecipitation  cathode material  specific capacity  cycle performance
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