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Study of stability of high‐temperature polyimides using TG/MS technique
Authors:Wei Xie  Rebecca Heltsley  Xinhua Cai  Fuquan Deng  Jiemin Liu  Charles Lee  Wei‐Ping Pan
Abstract:The oxidative stability of the carbon fiber‐reinforced composite of polyimide was examined, in real time, using the evolved gas analysis techniques. Off‐gas degradation products suggested the onset temperature for chain scissions to be fairly low at about 190–220°C. Based on the off‐gas products present and the trend of their release, the composite degradation mechanism appeared to be similar between 190 and 371°C, thereby marking 371°C to be the highest accelerated aging temperature for its long‐term lifetime prediction. Beyond 371°C, different degradation mechanisms would apply. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 1219–1227, 2002
Keywords:thermal analysis  polyimides  TGA  degradation
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