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Thermodynamics of Rubidium Uranoniobate
Authors:N. V. Karyakin  N. G. Chernorukov  E. V. Suleimanov  V. L. Trostin  A. V. Makarov  O. V. Feoktistova
Abstract:The standard enthalpies of formartion of crystalline agr-RbNbUO6, beta-RbNbUO6, and RbNbUO6·H2O at 298.15 K were determined. The temperature dependence of the heat capacity of agr-RbNbUO6, RbNbUO6·H2O, and beta-RbNbUO6 was studied in the range 60-300 K. The thermodynamic functions and equilibrium constants of the reactions involved in synthesis of rubidium uranoniobates at various temperatures were calculated.
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