Combustion of Na2B4O7 + Mg + C to synthesis B4C powders

Boron carbide powder was fabricated by combustion synthesis (CS) method directly from mixed powders of borax (Na₂B₄O₇), magnesium (Mg) and carbon. The adiabatic temperature of the combustion reaction of Na₂B₄O₇ + 6 Mg + C was calculated. The control of the reactions was achieved by selecting reactant composition, relative density of powder compact and gas pressure in CS reactor. The effects of these different influential factors on the composition and morphologies of combustion products were investigated. The results show that, it is advantageous for more Mg/Na₂B₄O₇ than stoichiometric ratio in Na₂B₄O₇ + Mg + C system and high atmosphere pressure in the CS reactor to increase the conversion degree of reactants to end product. The final product with the minimal impurities’ content could be fabricated at appropriate relative density of powder compact. At last, boron carbide without impurities could be obtained after the acid enrichment and distilled water washing.