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Research progress in the SO2resistance of the catalysts for selective catalytic reduction of NOx
Authors:Minhua Zhang  Baojuan Huang  Haoxi Jiang  Yifei Chen
Affiliation:1. Key Laboratory for Green Chemical Technology of Ministry of Education, R&D Center for Petrochemical Technology, Tianjin University, Tianjin 300072, China; 2. Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072, China
Abstract:The selective catalytic reduction(SCR)of NOxwith NH3has been proven to be an efficient technology for NOx conversion to N2.However,the catalysts used for SCR usually suffer from the problem of sulfur poisoning which seriously limits their practical application.This review summarized sulfur poisoning mechanisms of various SCR deNOxcatalysts and strategies to reduce deactivation caused by SO2such as doping metals,control-ling the structures and morphologies of the catalysts,and selecting appropriate supports.The methods and procedures of catalysts preparation and the reaction conditions also have effect on SO2-resistance of the catalysts. Several novel catalyst systems that exhibited good SO2resistance are also introduced.This paper could provide guidance for the development of highly efficient sulfur-tolerant deNOxcatalysts.
Keywords:Words Selective catalytic reduction(SCR)  SO2resistance  catalyst  NOx
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