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TiN涂层电化学腐蚀行为研究Ⅱ.添加Al对TiN涂层保护性能与失效机制的影响
引用本文:李瑛,屈力,王福会,邵忠宝. TiN涂层电化学腐蚀行为研究Ⅱ.添加Al对TiN涂层保护性能与失效机制的影响[J]. 中国腐蚀与防护学报, 2003, 23(3): 134-138
作者姓名:李瑛  屈力  王福会  邵忠宝
作者单位:1. 中国科学院金属研究所,金属腐蚀与防护国家重点实验室,沈阳,110016
2. 中国科学院金属研究所,金属腐蚀与防护国家重点实验室,沈阳,110016;东北大学理学院,沈阳,110006
3. 东北大学理学院,沈阳,110006
基金项目:国家自然科学基金面上基金资助课题 ( 5 0 0 0 10 13 )
摘    要:利用电化学方法以及扫描电镜 (SEM)、扫描隧道显微镜 (STM )技术等 ,研究了添加Al对离子镀TiN薄膜涂层在 0 5mol/LNaCl和 1mol/LH2 SO4溶液中的保护性能和失效机制的影响 ,发现铝的添加使TiN涂层在中性和酸性溶液中的耐蚀性能明显改善 .Al元素对TiN涂层具有自修复作用

关 键 词:Al元素  TiN涂层  保护性能  失效机制
文章编号:1005-4537(2003)03-0134-05
修稿时间:2002-10-22

STUDY ON THE ELECTROCHEMICAL CORROSION BEHAVIOR OF TiN COATING IN ACID AND SALT SOLUTION Ⅱ . The effect of Al addition on the corrosion resistance and failure mechanism of TiN coating in acid and salt solution
LI Ying ,QU Li ,,WANG Fuhui ,SHAO Zhongbao. STUDY ON THE ELECTROCHEMICAL CORROSION BEHAVIOR OF TiN COATING IN ACID AND SALT SOLUTION Ⅱ . The effect of Al addition on the corrosion resistance and failure mechanism of TiN coating in acid and salt solution[J]. Journal of Chinese Society For Corrosion and Protection, 2003, 23(3): 134-138
Authors:LI Ying   QU Li     WANG Fuhui   SHAO Zhongbao
Affiliation:LI Ying 1,QU Li 1,2,WANG Fuhui 1,SHAO Zhongbao 2
Abstract:The effect of Al addition on the corrosion properties of TiN coating was studied by electrochemical methods and surface analysis such as SEM and STM.It has been revealed that the structure of TiN coating has been changed from cylinder crystal to the crystal in nanometer.The corrosion property of TiN and (Ti,Al)N coatings are different.The general corrosion occurred on (Ti,Al)N coating in acid and salt solution,however,the corrosion behavior of TiN coating is similar to pit corrosion.The corrosion resistance of (Ti,Al)N has been improved for the self-repaired function of the (Ti,Al)N coating.The catalytic process under the (Ti,Al)N coating is not as serous as that under TiN coating.
Keywords:Ti  Al) N  corrosion resistance  failure mechanism
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