Multi‐Step Controlled Kinetics of the Transesterification of Crude Soybean Oil with Methanol by Mg(OCH3)2 |
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Authors: | K Huang Q‐L Xu S‐P Zhang Z‐W Ren Y‐J Yan |
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Affiliation: | Research Center for Biomass Energy, East China University of Science and Technology, Shanghai, P.R. China |
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Abstract: | This work focuses on a kinetic model that can be expressed as three significant controlled regions, i.e., a mass transfer controlled region in the internal surface of a heterogeneous catalyst, an irreversible chemical reaction controlled region in the pseudo‐homogenous fluid body and a reversible equilibrium chemical reaction controlled region near to the transesterification equilibrium stage. With the help of MATLAB7.0 software, the apparent reaction rate constants, k2, k2+ and k2–, were calculated and the corresponding apparent activation energies were calculated to be 67.450, 60.680 and 58.279 kJ·mol–1, respectively. According to the confirmation experiments, it is indicated that the results can be applied for predicting the FAME yield at other reaction temperatures. |
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Keywords: | Biodiesel Kinetics Magnesium methoxide Solid catalysts Transesterification |
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