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Poly(styrene‐co‐butyl acrylate) latex‐reinforced polyester nonwoven fabric composites: Thermal and morphological studies
Authors:M. N. Satheesh Kumar  Z. Yaakob  Siddaramaiah
Affiliation:1. Research and Innovation Center, Raman Boards Limited, Thandavapura, Mysore 571325, India;2. Faculty of Chemical and Process Engineering, National University of Malaysia (UKM), Bangi, Selangor 43600;3. Department of Polymer Science and Technology, Sri Jayachamarajendra College of Engineering, Mysore 570 006, India
Abstract:A series of thermoplastic composites were fabricated by impregnating the polyester nonwoven fabric in poly(styrene‐co‐butyl acrylate) latex having different monomer compositions of styrene and butyl acrylate viz., 100/0, 90/10, 80/20, 70/30, 60/40, and 50/50 weight by weight. Thermogravimetric analysis (TGA) of the composites was performed to establish the thermal stability and their mode of thermal degradation. From TGA thermograms, a slight improvement in thermal stability of the composites was noticed compared to polyester nonwoven fabric. Degradation kinetic parameters were obtained for the composites using Broido and Coats–Redfern methods. The activation energy (Ea) of the composites for the thermal degradation process lies in the range 7.1–261 and 60–264 kJ/mol for Broido and Coats–Redfern methods respectively. Morphology of the tensile‐fractured composites was studied using scanning electron microscopic technique. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009
Keywords:polyester nonwoven fabric  styrene/butyl acrylate  composites  TGA  kinetic parameter
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