| 一种新型含肉桂酸酯结构的螺吡喃光致变色染料的合成与性能研究 |
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| 引用本文： | 申凯华, ,崔东熏.一种新型含肉桂酸酯结构的螺吡喃光致变色染料的合成与性能研究[J].中国化学工程学报,2005,13(1):85-90. |
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| 作者姓名： | 申凯华 崔东熏 |
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| 作者单位： | [1]StateKeyLaboratoryofFineChemicals,DalianUniversityofTechnology,Dalian116012,China [2]CollegeofEnvironment＆AppliedChemistry,InstituteofNaturalSciences,KyungHeeUniversity,1Seocheon-ri,Kiheung-up,Yongin-shi,Kyungki,449-701,Korea |
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| 基金项目： | SupportedbytheKoreaResearchFoundation(KRF-2001-005-D00004). |
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| 摘 要： | A novel bifunctional dye containing spirobenzopyran and cinnaznoyl moiety has been prepared and its photochromic behavior following irradiation at different wavelengths of monochrome UV light was investigated.The colourless bifunctional dye in film or solution exhibits unusual photochromism through structural and geometrical transformation from spirobenzopyran to merocyanine accompanying with photocrosslinking reaction in cinnamoyl moieties. Two kinds of photochemical reaction were achieved by irradiation at the different wavelengths of monochrome UV light (275 nm, 365 nm) selectively. The photochromic process of the bifunctional dye was discussed and the dynamic behaviors of the decolorization process were investigated.
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| 关 键 词： | 染料 有机光化合物 光致交联反应 光化学反应 分析方法 生产工艺 |
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Synthesis and Characterization of a New Bifunctional Dye Containing Spirobenzopyran and Cinnamoyl Moiety |
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| SHEN Kaihua, ,CHOI Donghoon.Synthesis and Characterization of a New Bifunctional Dye Containing Spirobenzopyran and Cinnamoyl Moiety[J].Chinese Journal of Chemical Engineering,2005,13(1):85-90. |
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| Authors: | SHEN Kaihua CHOI Donghoon |
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| Affiliation: | State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China;College of Environment & Applied Chemistry, Institute of Natural Sciences, Kyung Hee University, 1 Seocheon-ri,Kiheung-up, Yongin-shi, Kyungki, 449-701, Korea |
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| Abstract: | A novel bifunctional dye containing spirobenzopyran and cinnamoyl moiety has been prepared and its photochromic behavior following irradiation at different wavelengths of monochrome UV light was investigated.The colourless bifunctional dye in film or solution exhibits unusual photochromism through structural and geometrical transformation from spirobenzopyran to merocyanine accompanying with photocrosslinking reaction in cinnamoyl moieties. Two kinds of photochemical reaction were achieved by irradiation at the different wavelengths of monochrome UV light (275 nm, 365 nm) selectively. The photochromic process of the bifunctional dye was discussed and the dynamic behaviors of the decolorization process were investigated. |
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| Keywords: | spirobenzopyran cinnamoyl moiety photochromism |
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