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Mg:Mn:Fe:LiNbO3晶体的全息存储性能
引用本文:郑威,桂强,徐玉恒,雷清泉. Mg:Mn:Fe:LiNbO3晶体的全息存储性能[J]. 硅酸盐学报, 2007, 35(8): 1013-1016
作者姓名:郑威  桂强  徐玉恒  雷清泉
作者单位:1. 哈尔滨理工大学材料与工程学院,哈尔滨,150040;哈尔滨工业大学应用化学系,哈尔滨,150001
2. 哈尔滨理工大学材料与工程学院,哈尔滨,150040
3. 哈尔滨工业大学应用化学系,哈尔滨,150001
基金项目:国家重点基础研究发展计划(973计划) , 黑龙江省自然科学基金
摘    要:在同成分铌酸锂晶体中掺入0.03?2O3和0.1%MnO2(质量分数),分别掺入0,1%,3%,4.5%,6%的MgO(摩尔分数),用提拉法生长了一系列Mg:Mn:Fe:LiNbO3晶体.检测了Mg:Mn:Fe:LiNbO3晶体的红外光谱和抗光损伤能力.掺0,1%,3%,4.5%Mg的Mg:Mn:Fe:LiNbO3晶体的OH-红外振动峰位于3484cm-1,而掺6%Mg的Mg:Mn:Fe:LiNbO3晶体红外振动峰移到3 535gm-1.采用波长为632nm的He-Ne激光器作为光源,通过二波耦合方法测试晶体的全息存储性能.结果表明:Mg:Mn:Fe:LiNbO3晶体的写入时间和动态范围随掺镁量的增加而显著减小,而光折变灵敏度略有上升,抗光损伤性能增强,其中掺镁量为3%Mg:Mn:Fe:LiNbO3晶体更适合作为全息存储介质.

关 键 词:镁锰铁掺杂铌酸锂晶体  提拉法  红外光谱  全息存储  magnesium,manganese and iron doped lithium niobate crystal  Czochralski method  infrared spectrum  holographic storage
文章编号:0454-5648(2007)08-1013-04
修稿时间:2007-04-15

HOLOGRAPHIC STORAGE PROPERTIES OF Mg:Mn:Fe:LiNbO3 CRYSTALS
ZHENG Wei,GUI Qiang,XU Yuheng,LEI Qingquan. HOLOGRAPHIC STORAGE PROPERTIES OF Mg:Mn:Fe:LiNbO3 CRYSTALS[J]. Journal of The Chinese Ceramic Society, 2007, 35(8): 1013-1016
Authors:ZHENG Wei  GUI Qiang  XU Yuheng  LEI Qingquan
Affiliation:1. College of Material Science and Engineering, Harbin University of Science and Technology, Harbin 150040; 2. Department of Applied Chemistry, Harbin Institute of Technology, Harbin 150001, China
Abstract:A series of lithium niobate (Mg:Mn:Fe:LiNbO3) crystal doped with 0.03 % Fe2O3 and 0.1 % MnO2 (in mass) and with dif-ferent the MgO contents of 0, 1%, 3%, 4.5% and 6 % in mole were grown by the Czochralski method from congruent melting. Their infrared spectrum and photodamage resistance ability were measured. The results show that the OH-absorption peak of the Mg(0, 1%, 3%, 4.51%):Mn:Fe:LiNbO3 crystals is at 3 484 cm-1, while that of 6% Mg doped Mg:Mn:Fe:LiNbO3 shifts to 3 535 cm-1. Holographic storage properties of crystals were measured with He-Ne laser at the wavelength of 632 m by two wave coupling method. The results show that the response time and dynamic range of crystals decrease, but photorefractive sensitivity and photodamage resistance ability improve with the increase of Mg doping concentration in crystals. Mg:Mn:Fe:LiNbO3 crystal with the optimal doping concentration of 3% Mg is suitable for holographic storage medium.
Keywords:magnesium  manganese and iron doped lithium niobate crystal  Czochralski method  infrared spectrum  holographic storage
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