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Comparison of pyrolysis and hydrothermal liquefaction of Chlamydomonas reinhardtii. Growth studies on the recovered hydrothermal aqueous phase
Affiliation:1. Department of Biosystems Engineering, Faculty of Bioscience Engineering, Ghent University, Coupure Links 653, B-9000 Ghent, Belgium;2. Institute for Catalysis Research and Technology, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmoltz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany;3. Conversion Technology and Life Cycle Assessment of Renewable Resources (440f), Institute of Agricultural Engineering, University Hohenheim, Garbenstrasse 9, 70599 Stuttgart, Germany
Abstract:The production of bio-oil by pyrolysis with a high heating rate (500 K s?1) and hydrothermal liquefaction (HTL) of Chlamydomonas reinhardtii was compared. HTL led to bio-oil yield decreasing from 67% mass fraction at 220 °C to 59% mass fraction at 310 °C whereas the bio-oil yield increased from 53% mass fraction at 400 °C to 60% mass fraction at 550 °C for pyrolysis. Energy ratios (energy produced in the form of bio-oil divided by the energy content of the initial microalgae) between 66% at 220 °C and 90% at 310 °C in HTL were obtained whereas it was in the range 73–83% at 400–550 °C for pyrolysis. The Higher Heating Value of the HTL bio-oil was increasing with the temperature while it was constant for pyrolysis. Microalgae cultivation in aqueous phase produced by HTL was also investigated and showed promising results.
Keywords:Pyrolysis  Hydrothermal liquefaction  Microalgae  Bio-oil production
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