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Electroactive shape memory polymer based on optimized multi-walled carbon nanotubes/polyvinyl alcohol nanocomposites
Affiliation:1. School of Material Science and Engineering, Wuhan Institute of Technology, Wuhan 430073, China;2. Department of Industrial and Systems Engineering, The Hong Kong Polytechnic University, Hung Hom, Hong Kong, China;3. State Key Laboratory of Materials Processing and Die & Mould Technology, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China;1. Science and Technology on Advanced Composites in Special Environments Laboratory, Harbin Institute of Technology, Harbin 150080, China;2. Composite Materials and Structures Laboratory, Department of Mechanical, Materials and Aerospace Engineering, University of Central Florida, Orlando, FL 32816, USA;3. Composite Material Research Laboratory, Department of Mechanical Engineering, University of New Orleans, LA 70148, USA;1. State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, Dongchuan Road No. 800, Shanghai 200240, China;2. Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai Jiao Tong University, China;3. University of Michigan-Shanghai Jiao Tong University Joint Institute, China;1. College of Aerospace and Civil Engineering, Harbin Engineering University, Harbin, China;2. School of Aerospace, Mechanical and Mechatronic Engineering, The University of Sydney, NSW 2006, Australia;1. Department of Astronautical Science and Mechanics, Harbin Institute of Technology (HIT), P.O. Box 301, No. 92 West Dazhi Street, Harbin 150001, China;2. Centre for Composite Materials and Structures, Science Park of Harbin Institute of Technology (HIT), P.O. Box 3011, No. 2 YiKuang Street, Harbin 150080, China;1. Science and Technology on Advanced Composites in Special Environments Laboratory, Harbin Institute of Technology, Harbin 150080, China;2. School of Mechanical and Aerospace Engineering, Nanyang Technological University, Singapore 639798, Singapore;3. Composite Material Research Laboratory, Department of Mechanical Engineering, University of New Orleans, LA 70148, USA
Abstract:The development of shape memory polymers (SMPs) has gained remarkable attention due to their wide range of applications, from biomedical to electromechanical. In this work, we have developed and optimized an electroactive SMP based on polyvinyl alcohol/multi-walled carbon nanotubes (PVA/MWNTs) composites. When a constant voltage of 60 V was applied to the optimized sample, the polymer shape could be recovered to the original form within 35 s. Different weight fractions of MWNT/PVA composites were prepared by using a simple solution blending and transitional solution casting method, and their microstructures, electrical conductivities, thermal conductivities, and electroactive shape memory properties were investigated. According to our systematic analysis, the enhanced performance can be attributed to the reinforcement of MWNTs that led to the improved electrical and thermal conductivities of the PVA matrix.
Keywords:A  Polymer-matrix composites (PMCs)  B  Physical properties  E  Casting
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