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Spray deposited ZnO and Ga doped ZnO based DSSC with bromophenol blue dye as sensitizer: Efficiency analysis through DFT approach
Affiliation:1. Centre for Nanotechnology & Advanced Biomaterials (CeNTAB), SASTRA University, Thanjavur 613401, Tamil Nadu, India;2. School of Electrical & Electronics Engineering, SASTRA University, Thanjavur 613401, Tamil Nadu, India;1. Department of Chemistry, Indian Institute of Technology (Banaras Hindu University), Varanasi 221005, U.P., India;2. Department of Chemistry, Faculty of Science, Banaras Hindu University, Varanasi 221005, U.P., India;1. Department of Physics, MESKEVEEYAM college Valanchery, Kerala, India;2. Department of Physics, University of Calicut, Kerala 673635 India;3. Department for Solar Energy, Institute for Energy Technology, Kjeller, Norway;4. UGC-DAE CSR, University Campus, Khandwa Road, Indore, India;5. Centre for Materials for Electronics and Technology (C-MET), Department of Information Technology, Athani, M.G. Kavu, Thrissure, Kerala, India;1. Department of Product Development, Phoenix Silicon International Corporation, Hsinchu 300, Taiwan, ROC;2. Department of Mechanical Engineering, National Taiwan University, Taipei 106, Taiwan, ROC;1. S. V. College, Aligarh, Dr. B. R. Ambedkar University, Agra, India;2. Department of Applied Physics, Aligarh Muslim University, Aligarh 202002, India;3. Department of Physics, Central University of Rajasthan, NH-8, Bandarsindri 305817, Rajasthan, India;1. Department of Physics, Faculty of Arts and Sciences, Düzce University, Düzce, Turkey;2. Department of Chemistry, Faculty of Arts and Sciences, Düzce University, Düzce, Turkey;3. Department of Chemistry, Faculty of Arts and Sciences, Bülent Ecevit University, Zonguldak, Turkey
Abstract:Dye sensitized solar cells based on spray deposited ZnO and Ga doped ZnO (GZO) thin film were fabricated with Bromophenol Blue as the photo sensitizer. XRD results show the hexagonal wurtzite phase of ZnO and GZO thin films with c-axis growth orientation, and the diminished crystalline nature of GZO thin film as the effect of doping. FE-SEM results revealed the morphology induced internal light interaction capability of GZO thin film for better harvesting of photon energy. Photovoltaic studies showed that the DSSC fabricated with GZO thin film has obtained enhanced power conversion efficiency (1%) than the ZnO thin film based DSSC (0.2%), as a result of Ga doping. To investigate the obtained photovoltaic performance of the device, the electronic properties of Bromophenol Blue dye were theoretically analyzed with Density Functional Theory (DFT) study.
Keywords:GZO  Bromophenol Blue  Dye sensitized solar cell  Density functional theory  Density of states
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