| 烯丙基碘与锡和醛的选择性加成 |
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| 引用本文： | 姚丹姝,商出岫.烯丙基碘与锡和醛的选择性加成[J].材料与冶金学报,1997(2). |
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| 作者姓名： | 姚丹姝 商出岫 |
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| 摘 要： | 烯丙基碘与锡和含有活性基团的醛可进行直接的亲核加成，水的存在不利于此反应的进行．比较了烯丙基碘、烯丙基溴进行反应时的活性，没想了烯丙基锡化物与羰基的加成反应机理．
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| 关 键 词： | 烯丙基碘 锡粉 活性基团 加成 |
Selective Addition of Aldehydes by Allyl Iodine And Tin |
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| Yao Dandshu, Shang Chuoxiu.Selective Addition of Aldehydes by Allyl Iodine And Tin[J].Journal of Materials and Metallurgy,1997(2). |
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| Authors: | Yao Dandshu Shang Chuoxiu |
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| Affiliation: | Department of Basic Sciences |
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| Abstract: | Allyl iodine and tin powder can react with aldehyde containing functional groups directly. The water is disadvantagous to the reationT. heactivity of alllyl bromide and. allyl iodine is compared. The nucleophilic addition process of alyl tin to carbonyl compounds is discussed. |
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| Keywords: | allyl iodine tin powder functional group addition |
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