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化学放大法测量大气过氧自由基的技术进展
引用本文:陈杨,赵卫雄,徐学哲,阳成强,林晓晓,盖艳波,张为俊.化学放大法测量大气过氧自由基的技术进展[J].大气与环境光学学报,2017,12(4):241-253.
作者姓名:陈杨  赵卫雄  徐学哲  阳成强  林晓晓  盖艳波  张为俊
作者单位:(1.安徽大学物理与材料科学学院,安徽 合肥 230601; 2.中国科学院安徽光学精密机械研究所,安徽 合肥 230031)
基金项目:Supported by National Natural Science Foundation of China ( 41375127, 91544228, 41575125), National Science Fund for Distinguished Young Scholars of Anhui Province of China
摘    要:大气过氧自由基(RO2)是大气化学过程中的关键中间体自由基,在对流层光化学反应中占有重要地位,因此,对相关测量技术的研究具有极其重要的意义。化学放大法是RO2测量中最常用的方法之一,是一种间接测量方法,通过在反应系统中加入过量的CO、NO气体,将低浓度、不易测量的过氧自由基通过链式反应转化为高浓度、易测量的NO2进行测量,NO2测量的准确性对化学放大法攸关重要。对化学放大法进行了总结,并着重分析了其中用于NO2测量的方法,分析了现有方法的优点与不足,并对未来的发展作了展望。

关 键 词:过氧自由基  化学放大法  NO2测量技术  
收稿时间:2016-04-08
修稿时间:2016-05-09

Advances in Chemical Amplification Measurement of Peroxy Radicals
CHEN Yang,ZHAO Wei-Xiong,XU Xue-Zhe,YANG Cheng-Qiang,LIN Xiao-Xiao,GAI Yan-Bo,ZHANG Wei-Jun.Advances in Chemical Amplification Measurement of Peroxy Radicals[J].Journal of Atmospheric and Environmental Optics,2017,12(4):241-253.
Authors:CHEN Yang  ZHAO Wei-Xiong  XU Xue-Zhe  YANG Cheng-Qiang  LIN Xiao-Xiao  GAI Yan-Bo  ZHANG Wei-Jun
Affiliation:(1. School of Physics and Materials Science, Anhui University, Hefei 230601, China;  2. Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China)
Abstract:Atmospheric peroxy radicals (RO2) are key intermediate radicals in the atmosphere, which occupy an important position in the tropospheric photochemical reaction processes. However, they are difficult to be measured because of their low concentration and high reactivity in the atmosphere. Chemical amplification, an indirect measurement technique, is one of the most commonly used methods of RO2 measurements. RO2 radicals are converted and amplified into high concentrations of stable NO2 via chain reactions by adding excess amount of CO and NO gas. Then the measurement of RO2 radicals could be achieved by measuring NO2 through different methods thatare welldeveloped. Chemical amplification is summarized, and different measurement methods of NO2 with their advantages and disadvantages are emphatically compared and analyzed. Finally, the directions for future research are prospected.
Keywords:peroxy radical  chemical amplification  NO2 measurement  
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