| 胺与甲酸氮甲酰化反应催化剂的研究 |
| |
| 引用本文： | 沈凤翠,任一鸣,张荣莉.胺与甲酸氮甲酰化反应催化剂的研究[J].广东化工,2011(8):81-83. |
| |
| 作者姓名： | 沈凤翠 任一鸣 张荣莉 |
| |
| 作者单位： | 安徽工程大学生物与化学工程学院; |
| |
| 基金项目： | 安徽工程大学青年基金项目(2010YQ043) |
| |
| 摘 要： | 氮甲酰化反应是有机合成化学中的重要反应，而催化剂的选择是氮甲酰化反应的关键所在。文章综述了无机氧化物，聚合物PEG-400，Lewis酸，树脂AmberliteIR-120，无机盐。VBl催化合成氮甲酰化产物的研究成果。不同的催化剂在活性、选择性、稳定性等方面各有特点，其中绿色高效可回收利用的催化剂是该领域的主要研究方向。
|
| 关 键 词： | 胺 氮甲酰化 甲酸：催化合成 |
A Study of Catalysis on the N-formylation of Amines and Formic Acid |
| |
| Shen Fengcui,Ren Yiming,Zhang Rongli.A Study of Catalysis on the N-formylation of Amines and Formic Acid[J].Guangdong Chemical Industry,2011(8):81-83. |
| |
| Authors: | Shen Fengcui Ren Yiming Zhang Rongli |
| |
| Affiliation: | Shen Fengcui,Ren Yiming,Zhang Rongli(Chemical and Biological Technology,Anhui Polytechnic University Institute,Wuhu 241000,China) |
| |
| Abstract: | Formylation of amines is an important reaction in synthetic organic chemistry.The selection of catalyst system is the key of synthetic.Recent development in N-formyl reaction by catalytic synthesis was introduced in the paper.Research results of catalytic synthesis formamides by heterogeneous catalysts,immobilized inorganic oxides polyethylene glycol,Amberlite IR-120,Lewis acids,inorganic salts and VB1 were also reviewed.These results showed that different catalysts had their own properties on activity,sele... |
| |
| Keywords: | amines N-formylation formic acid catalytic synthesis |
| 本文献已被 CNKI 维普 等数据库收录！ |
|
