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Density of liquid NiCoAlCr quartemary alloys measured by modified sessile drop method
引用本文:方亮 张淑芳 肖锋 杨凌川 董建新 曹春兰 陶再南 K.MUKAI. Density of liquid NiCoAlCr quartemary alloys measured by modified sessile drop method[J]. 中国有色金属学会会刊, 2006, 16(A03): 1962-1966
作者姓名:方亮 张淑芳 肖锋 杨凌川 董建新 曹春兰 陶再南 K.MUKAI
作者单位:[1]Department of Applied Physics, Chongqing University, Chongqing 400044, China [2]Chongqing Institute of Technology, Chongqing 400050, China [3]Department of Physics, Chongqing Communication Institute, Chongqing 400035, China; [4]Satellite Venture Business Laboratory, Kyushu Institute of Technology, Kitakyushu 804-8550, Japan
基金项目:Foundation item: Project(NCET-05-0764) supported by the Program for New Century Excellent Talent in University; project(2004527) supported by SRF for R0CS, SEM
摘    要:The densities of liquid NiCoAlCr quaternary alloys with a fixed molar ratio of Ni to Co to Al (x(Ni):x(Co):x(Al)≈ 73:12:15) which is close to the average value of the commercial Ni-based superalloys TMS75, INCO713, CM247LC and CMSX-4, and the mass fraction of chromium changes from 0 to 9% were measured by a modified sessile drop method. It is found that with increasing temperature and chromium concentration in the alloys, the densities of the liquid NiCoAICr quaternary alloys decrease, whereas the molar volume of the liquid NiCoAICr quaternary alloys increases. And the liquid densities of NiCoAICr quaternary alloys calculated from the partial molar volumes of nickel, cobalt, aluminum and chromium in the corresponding Ni-bases binary alloys are in good agreement with the experimental ones, i.e. within the error tolerance range the densities of the liquid Ni-based multi-component alloys can be predicted from the partial volumes of elements in Ni-based binary alloys in liquid state. The molar volume of liquid NiCoAICr binary alloy shows a negative deviation from the ideal linear mixing and the deviation changes small with the increase of chromium concentration at the same temperature.

关 键 词:钴合金 有色金属 液相 抗热性
收稿时间:2006-07-28
修稿时间:2006-09-15

Density of liquid NiCoAlCr quartemary alloys measured by modified sessile drop method
FANG Liang, ZHANG Shu-fang, XIAO Feng, YANG Ling-chuan, DONG Jian-xin, CAO Chun-lan, TAO Zai-nan, K. MUKAI. Density of liquid NiCoAlCr quartemary alloys measured by modified sessile drop method[J]. Transactions of Nonferrous Metals Society of China, 2006, 16(A03): 1962-1966
Authors:FANG Liang   ZHANG Shu-fang   XIAO Feng   YANG Ling-chuan   DONG Jian-xin   CAO Chun-lan   TAO Zai-nan   K. MUKAI
Abstract:
Keywords:NiCoAlCr alloy   liquid density   liquid state   sessile drop method   molar volume
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