Applications of planar-chiral heterocycles as ligands in asymmetric catalysis |
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| Authors: | Fu Gregory C |
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| Affiliation: | Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA. gcf@mit.edu |
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| Abstract: | A new family of ligands for asymmetric transition metal-catalyzed reactions has been designed and synthesized. Thus, planar-chiral heterocycles furnish high enantioselectivity in a variety of processes, including isomerizations of allylic alcohols, O-H insertions, and 1,3-dipolar cycloadditions. |
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