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The effect of a novel organic compound chiral macrocyclic tetraamide-I interfacial layer on the calculation of electrical characteristics of an Al/tetraamide-I/p-Si contact
Affiliation:1. Department of Physics, Faculty of Science & Art, University of Dicle, Diyarbak?r 21280, Turkey;2. Department of Chemistry, Faculty of Education, University of Dicle, Diyarbak?r 21280, Turkey;3. Department of Electrical and Electronics Engineering, Faculty of Engineering, University of Dumlup?nar, Kütahya, Turkey
Abstract:The Al/tetraamide-I/p-Si Schottky barrier diode (SBD) has been prepared by adding a solution of a novel nonpolymeric organic compound chiral macrocylic tetraamide-I in chloroform on top of a p-Si substrate and then evaporating the solvent. It has been seen that the forward-bias current–voltage (IV) characteristics of Al/tetraamide-I/p-Si SBD with a barrier height value of 0.75 eV and an ideality factor value of 1.77 showed rectifying behaviour. The energy distribution of the interface state density determined from IV characteristics increases exponentially with bias from 5.81 × 1012 cm?2 eV?1 at (0.59-Ev) eV to 1.02 × 1013 cm?2 eV?1 at (0.40-Ev) eV. It has showed that space charge limited current (SCLC) and trap charge limited current (TCLC) are the dominant transport mechanisms at large forward-bias voltages.
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