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高性能PVC/PSf共混超滤膜的研制——(Ⅰ)稀溶液黏度法测PVC/PSf共混相容性的研究
引用本文:迟莉娜,奚旦立,陈季华,张振家.高性能PVC/PSf共混超滤膜的研制——(Ⅰ)稀溶液黏度法测PVC/PSf共混相容性的研究[J].高分子材料科学与工程,2006,22(5):132-135.
作者姓名:迟莉娜  奚旦立  陈季华  张振家
作者单位:上海交通大学环境科学与工程学院,上海,200240;东华大学环境科学与工程学院,上海,200051
摘    要:首次采用稀溶液黏度法(DSV法),通过相对黏度-组成曲线、增比黏度-浓度曲线,以及值对PVC与PS f的相容特性进行了研究。结果表明,PVC/PS f共混体系为部分相容体系,体系相容性随PVC/PS f共混比的增大而增加;溶液浓度和温度对PVC/PS f体系的相容性存在一定的影响。

关 键 词:稀溶液黏度法  聚氯乙烯/聚砜  共混相容性  合金膜
文章编号:1000-7555(2006)05-0132-04
收稿时间:2005-07-19
修稿时间:2006-05-16

Study on the Miscibility of Poly(Vinyl Chloride) and Poly Sulfone by Means of Dilute Solution Viscometry
CHI Li-na,XI Dan-li,CHEN Ji-hua,ZHANG Zhen-jia.Study on the Miscibility of Poly(Vinyl Chloride) and Poly Sulfone by Means of Dilute Solution Viscometry[J].Polymer Materials Science & Engineering,2006,22(5):132-135.
Authors:CHI Li-na  XI Dan-li  CHEN Ji-hua  ZHANG Zhen-jia
Affiliation:1. School of Environmental Science and Engineering, Shanghai Jiaotong University, Shanghai 200240, China; 2. School of Environmental Science and Engineering, Donghua University, Shanghai 200051, China
Abstract:For the solution viscometry. first time the miscibility of PVC and PSf was investigated by means of dilute Reduced viscosity-concentration plots, viscosity-composition plots and the calculated value of AB were used to deal with the experimental data. It is demonstrated that PVC and PSf possesses partial miscibility depending on and influenced by blend ratio, concentration of polymers in solution, temperature, etc.. The miscibility of the systems with PVC/PSf mass ratio more than 1 is superior to such systems with the ratio less than 1.
Keywords:DSV  PVC/PSf  miscibility of polymer blends  alloy membranes  
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