| 甲基丙烯酸甲酯与尼龙接枝共聚反应的研究 |
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| 引用本文： | 张福莲,杨椰林,赵征,陈丹云,王浩,张举贤. 甲基丙烯酸甲酯与尼龙接枝共聚反应的研究[J]. 高分子材料科学与工程, 2002, 18(1): 159-160,164 |
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| 作者姓名： | 张福莲 杨椰林 赵征 陈丹云 王浩 张举贤 |
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| 作者单位： | 河南大学化学化工学院,河南,开封,475001;开封市卫校,河南,开封,475000 |
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| 基金项目： | 国家自然科学基金资助项目 (2 97740 0 6 ) |
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| 摘 要： | 研究了过氧化二苯甲酰 (BPO)引发的甲基丙烯酸甲酯与醇溶性尼龙在乙醇中的接枝共聚反应 ,探讨了单体浓度、引发剂浓度对接枝率的影响。并由红外光谱、X射线衍射分析对接枝共聚产物进行了结构表征
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| 关 键 词： | 尼龙 接枝共聚 甲基丙烯酸甲酯 |
| 文章编号： | 1000-7555(2002)01-0159-02 |
| 修稿时间： | 2000-05-08 |
STUDY ON THE GRAFT COPOLYMERIZATION OF METHYL METHACRYLATE WITH NYLON |
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| ZHANG Fu lian ,YANG Ye lin ,ZHAO Zheng,CHEN Dan yun ,WANG Hao,ZHANG Ju xian. STUDY ON THE GRAFT COPOLYMERIZATION OF METHYL METHACRYLATE WITH NYLON[J]. Polymer Materials Science & Engineering, 2002, 18(1): 159-160,164 |
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| Authors: | ZHANG Fu lian YANG Ye lin ZHAO Zheng CHEN Dan yun WANG Hao ZHANG Ju xian |
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| Affiliation: | ZHANG Fu lian 1,YANG Ye lin 2,ZHAO Zheng,CHEN Dan yun 1,WANG Hao,ZHANG Ju xian 1 |
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| Abstract: | The grafting copolymerization of acrylic monomers with nylon was studied in order to obtain a new polymer material that has desirable properties of both acrylic resin and polyamide. The grafting copolymer may be useful as a component of printing inks, adhesives and leather coating compositions. In this article, methyl methacrylate was grafted onto an alcohol soluble nylon. The graft copolymerization was initiated by BPO in an ethanol solution, and the graft copolymer was characterized by the IR spectrum and X ray diffraction analysis. The effect of monomer and initiator concentrations on the graft efficiency was investigated. The results show that graft efficiency increases with the increase of monomer and/or initiator concentration, but the desired high graft efficiency has not been reached. |
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| Keywords: | nylon graft copolymerization methyl methacrylate |
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