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Hydrocarbon synthesis over sulfide catalysts. Break-down of the Anderson-Schulz-Flory distribution |
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| Authors: | P E Højlund Nielsen Karsten Pedersen J R Rostrup-Nielsen |
| Affiliation: | (1) Haldor Topsøe A/S, DK-2800 Lyngby, Denmark;(2) Danish Technological Institute, DK-8000 Aarhus, Denmark;(3) Haldor Topsøe A/S, DK-2800 Lyngby, Denmark |
| Abstract: | The kinetics of hydrocarbon synthesis over sulfide-based catalysts was studied. It appears that the formation of methane follows another reaction path than that of higher hydrocarbons. This might explain the very high selectivities for ethane and propane as compared with conventional Fischer-Tropsch catalysts. Reference is made to testing of the catalysts at industrial conditions. |
| Keywords: | hydrocarbon synthesis methanation ethanation sulfide catalysts hydrocarbon distribution Anderson-Schulz-Flory distribution |
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