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Preparation of highly stable superhydrophobic TiO2 surfaces with completely suppressed photocatalytic activity
Authors:Kwang-Dae Kim  Hyun Ook Seo  Chae Won Sim  Myung-Geun Jeong  Young Dok Kim  Dong Chan Lim
Affiliation:1. Department of Chemistry, Sungkyunkwan University, Suwon 440-746, Republic of Korea;2. Materials Processing Division, Korea Institute of Materials Science, Changwon 641-010, Republic of Korea
Abstract:TiO2 nanoparticles with a mean size of 20–30 nm were covered by ultrathin polydimethylsiloxane (PDMS) film, which shows hydrophobic properties. Surfaces consisting of the PDMS-coated TiO2 particles showed water contact angles close to 170°. In contrast to the hydrophobic films consisting of organic molecules, which can be photocatalytically decomposed on TiO2 in the presence of UV light, PDMS-coating on TiO2 was highly stable. The PDMS-coating completely suppressed the photocatalytic activity of TiO2. The unique properties of PDMS-coating can be exploited for UV protection layer and self-cleaning surfaces.
Keywords:Superhydrophobicity   Polydimethylsiloxane coating   Photocatalysis   TiO2   Nanostructures
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