2,4-二氨基嘧啶对冷轧钢在HCl溶液中的缓蚀作用 |
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引用本文: | 李向红,谢小光. 2,4-二氨基嘧啶对冷轧钢在HCl溶液中的缓蚀作用[J]. 腐蚀与防护, 2016, 0(12): 949-955. DOI: 10.11973/fsyfh-201612001 |
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作者姓名: | 李向红 谢小光 |
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作者单位: | 1. 西南林业大学理学院,昆明650224;云南大学化学科学与工程学院,昆明650091;2. 云南大学化学科学与工程学院,昆明,650091 |
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基金项目: | 国家自然科学基金项目(51361027),西南林业大学科研启动基金项目(111435),云南省中青年学术和技术带头人后备人才项目(2015HB049) |
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摘 要: | 通过浸泡试验、电化学试验和扫描电子显微镜(SEM)观察研究了2,4-二氨基嘧啶(DAP)在1.0mol/L HCl溶液中对冷轧钢的缓蚀作用。结果表明:DAP在HCl溶液中对冷轧钢具有良好的缓蚀作用;缓蚀率随缓蚀剂含量的增大而增大,DAP浓度为10.0mmol/L时缓蚀率最大,可达94.8%;DAP为混合型抑制型缓蚀剂,DAP在冷轧钢表面的吸附符合Langmuir吸附等温式,缓蚀率随温度的升高而下降。
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关 键 词: | 冷轧钢 HCl溶液 2,4-二氨基嘧啶 缓蚀 吸附 |
Corrosion Inhibition of 2,4-Diaminopyrimidine to Cold Rolled Steel in HCl Solution |
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Abstract: | The corrosion inhibition of 2,4-diaminopyrimidine (DAP) to cold rolled steel (CRS) in 1.0 mol/L HCl solution was studied through immersion test,electrochemical test and scanning electron microscopy (SEM).The results show that DAP was a good inhibitor for CRS in HCl solution.The inhibition efficiency increased with the increase of the concentration of DAP,and the maximum inhibition efficiency could reach as high as 94.8% when the concentration of DAP was 10.0 rnmol/L.DAP acted as a mixed-type inhibitor and the adsorption of DAP on the surface of cold rolled steel obeyed Langmuir adsorption isotherm.As the temperature rose,the inhibition efficiency decreased. |
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Keywords: | cold rolled steel HCl solution 2,4-diaminopyrimidine (DAP) corrosion inhibition adsorption |
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