Mechanochemical combustion synthesis of vanadium carbide (VC), niobium carbide (NbC) and tantalum carbide (TaC) nanoparticles

The nanoparticles of vanadium, niobium, and tantalum carbides were synthesized by a mechanically induced magnesiothermic combustion in the separate Mg/V₂O₅/C, Mg/Nb₂O₅/C, and Mg/Ta₂O₅/C systems. Initial materials in these systems ignited after short milling times of 10, 10, and 23 min, respectively. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), energy-dispersive X-ray spectroscopy (EDS), high-resolution transmission electron microscopy (HRTEM) and elemental mapping techniques were employed to characterize the combustion products. In this process, magnesium reduces initial oxides to generate elemental V/Nb/Ta to react with carbon, forming the carbide phases.